Free radicals formed in the reaction of 1H-1-oxo-2,4,6,8-tetrakis(tert-butyl)phenoxazine and 1-hydroxy-2,4,6,8-tetrakis(tert-butyl)phenoxazinyl radical with certain organometallic compounds

Autor:	E. P. Ivakhnenko, A. Z. Rubezhov, M. I. Kabachnik, A. I. Prokof'ev, V. S. Khandkarova, O. Yu. Okhlobystin, Vladimir I. Minkin, I. V. Karsanov
Rok vydání:	1987
Předmět:	Ligand Radical General Chemistry Resonance (chemistry) Medicinal chemistry Chemical reaction law.invention chemistry.chemical_compound chemistry Unpaired electron law Organic chemistry Electron paramagnetic resonance Phenoxazine Group 2 organometallic chemistry
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 36:56-60
ISSN:	1573-9171 0568-5230
Popis:	1. 1H-1-Oxo-2,4,6,8-tetrakis(tert-butyl)phenoxazine undergoes ligand exchange reactions and behaves as a spin trap for metal-centered radicals, as a result of which stable paramagnetic complexes are formed with delocalization of the unpaired electron in the organic ligand. 2. Paramagnetic complexes are also formed as the result of a reaction between potassium salt (IA) and triphenyl-tin and triphenyl-lead monochlorides.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::8cccb1d529c788981de0864e9c3fa46c https://doi.org/10.1007/bf00953845 Zobrazit plný text záznamu Full text from SpringerLink