Triisopropylsilyl (TIPS) Alkynes as Building Blocks for Syntheses of Platinum Triisopropylsilylpolyynyl and Diplatinum Polyynediyl Complexes

Autor:	Helene Kuhn, Frank Hampel, Andreas Ehnbom, John A. Gladysz, Hashem Amini, Nancy Weisbach, Joseph H. Reibenspies, Michael B. Hall
Rok vydání:	2019
Předmět:	Inorganic Chemistry Coupling (electronics) chemistry 010405 organic chemistry Organic Chemistry Polymer chemistry chemistry.chemical_element Physical and Theoretical Chemistry 010402 general chemistry Platinum 01 natural sciences 0104 chemical sciences
Zdroj:	Organometallics. 38:3294-3310
ISSN:	1520-6041 0276-7333
Popis:	Hay oxidative cross coupling (O2/CuCl/TMEDA) of trans-(p-tol)(p-tol3P)2Pt(C≡C)2H (PtTC4H) and excess H(C≡C)2Si-i-Pr3 (TIPSC4H) gives PtTC8TIPS (55%). Subsequent addition of n-Bu4N+F– and repetition...
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::8a862d72baf1a31d5d78a7d3ac3bbd9f https://doi.org/10.1021/acs.organomet.9b00368 Zobrazit plný text záznamu