Integrated infrared intensities and transition moments in SF6
Autor: | Kwan Kim, R. S. McDowell, W. T. King |
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Rok vydání: | 1980 |
Předmět: | |
Zdroj: | The Journal of Chemical Physics. 73:36-41 |
ISSN: | 1089-7690 0021-9606 |
DOI: | 10.1063/1.439883 |
Popis: | The integrated infrared band intensities of the fundamental vibrational modes in SF6 have been measured by the Wilson–Wells–Penner–Weber method. The results are 1361±34 km mole−1 for the fundamental at 948 cm−1, and 74±2 km mole−1 for the fundamental at 615 cm−1. The transition moments derived from these measurements are 0.437±0.005 D for the 948 cm−1 fundamental and 0.126±0.002 D for the 615 cm−1 band. The transition moment was also derived from single line strengths in the 948 cm−1 band and found to be 0.42±0.03 D, in good agreement with the value found from band intensities. |
Databáze: | OpenAIRE |
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