Integrated infrared intensities and transition moments in SF6

Autor:	Kwan Kim, R. S. McDowell, W. T. King
Rok vydání:	1980
Předmět:	Chemistry Infrared Molecular vibration Excited state Transition dipole moment General Physics and Astronomy Infrared spectroscopy Physical and Theoretical Chemistry Atomic physics Single line Spectral line
Zdroj:	The Journal of Chemical Physics. 73:36-41
ISSN:	1089-7690 0021-9606
DOI:	10.1063/1.439883
Popis:	The integrated infrared band intensities of the fundamental vibrational modes in SF6 have been measured by the Wilson–Wells–Penner–Weber method. The results are 1361±34 km mole−1 for the fundamental at 948 cm−1, and 74±2 km mole−1 for the fundamental at 615 cm−1. The transition moments derived from these measurements are 0.437±0.005 D for the 948 cm−1 fundamental and 0.126±0.002 D for the 615 cm−1 band. The transition moment was also derived from single line strengths in the 948 cm−1 band and found to be 0.42±0.03 D, in good agreement with the value found from band intensities.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::89ed47cd02b66241996e49291904495e https://doi.org/10.1063/1.439883 Zobrazit plný text záznamu