Absorption of carbon monoxide, hydrogen, and methane in toluene and copper(I) tetrachloroaluminate-toluene solutions at elevated pressures

Autor:	Martin Henschke, Juergen Koschel, Hugo Hartmann, Andreas Pfennig
Rok vydání:	1991
Předmět:	Hydrogen General Chemical Engineering Inorganic chemistry Energy Engineering and Power Technology chemistry.chemical_element Chemical reaction Toluene Copper chemistry.chemical_compound Fuel Technology chemistry Tetrachloroaluminate Solubility Absorption (chemistry) Carbon monoxide
Zdroj:	Energy & Fuels. 5:729-733
ISSN:	1520-5029 0887-0624
DOI:	10.1021/ef00029a018
Popis:	Solubilities of the coal-gasification products CO, H 2 , and CH 4 in pure toluene have been measured at temperatures between 249 and 343 K and pressures up to 7 MPa. Phase equilibria of CO and copper(I) tetrachloroaluminate-toluene solutions are presented between 254 and 333 K and pressures up to 9.5 MPa. In this absorbent, reversible chemical reactions occur resulting in a formation of several bimetallic salt complexes having a high bonding capacity for CO. Solubility measurements with H 2 and CH 4 in this agent show that these gases do not undergo any chemical reaction
Databáze:	OpenAIRE
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