K and Cs Doped Ag/Al2O3Catalyst for Selective Catalytic Reduction of NOx by Methane

Autor: Choi Hee Lack, Chang Yong Yu, Heon Phil Ha, Komateedi N. Rao
Rok vydání: 2011
Předmět:
Zdroj: Journal of Korean Powder Metallurgy Institute. 18:510-516
ISSN: 1225-7591
DOI: 10.4150/kpmi.2011.18.6.510
Popis: In the present study, potassium and caesium doped Ag/ catalysts were synthesized by simple wet impregnation method and evaluated for selective catalytic reduction (SCR) of NOx using methane. TEM analysis and diffraction patterns demonstrated the finely dispersed Ag particles. BET surface measurements reveal that the prepared materials have moderate to high surface area and the metal amount found from ICP analysis was well matching with the theoretical loadings. The synthesized K-Ag/ and Cs-Ag/ catalysts exhibited a promotional effect on deNOx activity in the presence of and . The long-term isothermal studies at under oxygen rich condition showed the superior catalytic properties of the both alkali promoted samples. The crucial catalytic properties of materials are attributed to NO adsorption properties detected by the NO TPD.
Databáze: OpenAIRE