Pulsed nuclear magnetic resonance signals in magnetically ordered materials

Autor: V. M. Kolesenko, V. S. Kuz’min, E. P. Borbotko
Rok vydání: 2008
Předmět:
Zdroj: Journal of Applied Spectroscopy. 75:550-559
ISSN: 1573-8647
0021-9037
DOI: 10.1007/s10812-008-9075-9
Popis: We have obtained an analytical expression for nuclear precession and nuclear echo signals generated in magnetically ordered materials upon resonant excitation of the nuclear subsystem by two pulses of identical amplitude but different durations. We show that in a nuclear subsystem with inhomogeneous broadening of the spectroscopic transition and an inhomogeneous gain distribution, the two-pulse precession and echo signals are split into four and nine components respectively. We have analytically established a correlation between the macroscopic parameters of the components of the two-pulse signals (relative amplitudes, signal formation times) and the microscopic parameters of the magnetically ordered media (inhomogeneous half-width of the spectral line, half-width of the gain distribution function, average gain). The theoretically calculated formation times for the components of the nuclear precession and nuclear echo signals agree with the experimental data obtained for the alloy FeNiCo (70% Co).
Databáze: OpenAIRE