Synthesis of Lanthanide(III) Chelates by Using ‘Click’ Chemistry
| Autor: | Harri Hakala, Janne Ketola, Johanna Katajisto, Jari Hovinen |
|---|---|
| Rok vydání: | 2007 |
| Předmět: |
Lanthanide
chemistry.chemical_classification Organic Chemistry Inorganic chemistry chemistry.chemical_element Alkyne Terbium Biochemistry Catalysis Cycloaddition Inorganic Chemistry chemistry.chemical_compound chemistry Drug Discovery Polymer chemistry Dysprosium Click chemistry Azide Physical and Theoretical Chemistry Europium |
| Zdroj: | Helvetica Chimica Acta. 90:607-615 |
| ISSN: | 1522-2675 0018-019X |
| DOI: | 10.1002/hlca.200790062 |
| Popis: | The copper(I)-catalyzed dipolar [2+3] cycloaddition reaction of an azide and a terminal alkyne is exploited in the preparation of various europium(III), terbium(III), and dysprosium(III) chelates (Schemes 1–3). By changing the nature of the alkyne and the azide, a wide range of chelates and biomolecule-labeling reactants were obtained. The photophysical properties (Table) of the synthesized chelates are also discussed. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Plný text