Phenylmercury derivatives of aminomethylene- and hydroxymethylene-substituted 1-methyloxindoles, 1-indanones, and 1,3-indanediones

Autor: Vladimir I. Minkin, Zh. V. Bren, L. M. Sitkina, Vladimir A. Bren
Rok vydání: 1979
Předmět:
Zdroj: Chemistry of Heterocyclic Compounds. 15:56-59
ISSN: 1573-8353
0009-3122
DOI: 10.1007/bf00471199
Popis: A number of phenylmercury derivatives of 3-hydroxymethylene- and 3-aminomethylene-substituted 1-methyloxindoles, 1-indanones, and 1,3-indanediones were synthesized. It is shown that the preferred tautomeric structures of the potentially metallotropic and prototropic hydroxymethylene keto (hydroxy vinyl aldehyde) derivatives of the indicated compounds and 3-hydroxybenzo[b]-2-formylthiophene coincide precisely. An aminomethylene structure with an N-H bond is realized for the phenylmercury derivatives of the corresponding azomethines in all cases.
Databáze: OpenAIRE