Ligand-Acceleration by a Chiral Modifier in the Enantioselective Hydrogenation of Methyl Acetoacetate on a Raney Nickel Catalyst: Effect of a Modifier Configuration

Autor: Ryo-Ichi Tsukiyama, Satoshi Nakagawa, Naoya Kamata, Tadashi Okuyama, Takashi Sugimura, Takahiro Tei, Takashi Tajiri, Yasuaki Okamoto
Rok vydání: 2015
Předmět:
Zdroj: Bulletin of the Chemical Society of Japan. 88:271-276
ISSN: 1348-0634
0009-2673
Popis: Reaction rate and enantioselectivity of asymmetric hydrogenation of methyl acetoacetate were studied over Raney nickel catalysts modified with (R,R)-tartaric acid, malic acid, or succinic acid to r...
Databáze: OpenAIRE