Evidence for the intermediacy of 1,1-dimethyl-2-phenyl-1-sila-1,3-butadiene in the photochemistry and pyrolysis of 1,1-dimethyl-2-phenyl-1-sila-2-cyclobutene

Autor:	Raymond H Fong, William P. Weber, H.S.Dilanjan Soysa, Dongjaw Tzeng
Rok vydání:	1981
Předmět:	Cyclobutene Organic Chemistry Photodissociation Formaldehyde 1 3-Butadiene Photochemistry Biochemistry Silane Inorganic Chemistry chemistry.chemical_compound chemistry Materials Chemistry Acetone Organic chemistry Methanol Physical and Theoretical Chemistry Pyrolysis
Zdroj:	Journal of Organometallic Chemistry. 219:153-161
ISSN:	0022-328X
Popis:	Photolysis of 1,1-dimethyl-2-phenyl-1-sila-2-cyclobutene (I) in methanol and methanol-O- d 1 yields dimethylmethoxy(1-phenyl-2-propenyl)silane and dimethylmethoxy(1- d 1 -1-phenyl-2-propenyl)silane, respectively, as major products. These products may be formed by reaction of methanol or methanol-O- d 1 with 1,1-dimethyl-2-phenyl-1-sila-1,3-butadiene. Gas phase pyrolysis of I and acetone or formaldehyde have also been studied.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::7acbec7c6e07e043fd07d584e41606ac https://doi.org/10.1016/s0022-328x(00)83007-7 Zobrazit plný text záznamu