Interacting metal and ligand based open shell systems: Challenges for experiment and theory
| Autor: | Alexa Paretzki, Wolfgang Kaim |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
chemistry.chemical_classification
010405 organic chemistry Ligand Inorganic chemistry 010402 general chemistry Electrochemistry 01 natural sciences Redox 0104 chemical sciences Coordination complex Inorganic Chemistry Metal Transition metal chemistry Chemical physics visual_art Materials Chemistry visual_art.visual_art_medium Physical and Theoretical Chemistry Spin (physics) Open shell |
| Zdroj: | Coordination Chemistry Reviews. 344:345-354 |
| ISSN: | 0010-8545 |
| DOI: | 10.1016/j.ccr.2016.12.008 |
| Popis: | Three-center bridged situations Ru-L-Ru and Q-M-Q (M = Ru, Co, Ni, Cu) containing redox-active transition metals and noninnocently behaving ligand redox systems Lk or Qn (o-iminoquinone/o-iminosemiquinone/o-amidophenolate series) can provide valuable insight into electronic and spin interactions of correlated coordination compounds. Experimental approaches using combined structural, electrochemical, spectroscopic (UV–vis-NIR) and magnetic resonance methods were employed with computational support to elucidate which of the potential alternatives are most appropriate to describe the individual electronic structures. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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