ChemInform Abstract: Rearrangement of 3-Ethoxycarbonyl-5-hydroxyimino-2-methyl-4-oxonaphtho[1,2-b]furan and 3-Ethoxycarbonyl-5-hydroxyimino-2-methyl-4-oxo-1-phenylbenzo[g]indole by the Action of Benzenesulfonyl Chloride in an Alkaline Medium

Autor:	A. P. Stankyavichus, L. M. M. Stankyavichene, P. B. Terent'ev
Rok vydání:	2010
Předmět:	Indole test chemistry.chemical_compound chemistry Furan Beckmann rearrangement Benzenesulfonyl chloride Mass spectrum Organic chemistry General Medicine Pyrrole derivatives
Zdroj:	ChemInform. 31
ISSN:	1522-2667 0931-7597
Popis:	The treatment of 3-ethoxycarbonyl-2-methyl-4,5-dioxonaphtho[1,2-b]furan 5-monoximes and also the similarly substituted benzo[g]indole with benzenesulfonyl chloride in an alkaline medium give 5-(2-cyanophenyl)-3-ethoxycarbonyl-2-methylfuran-4-carboxylic and pyrrole-4-carboxylic acids with high yields as a result of a second-order Beckmann rearrangement. The structures of the initial and final compounds were confirmed by analysis of their mass spectra.
Databáze:	OpenAIRE
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