Influence of chemically inert fillers on the efficiency of polyethylene inhibition by antioxidants

Autor:	D. G. Lin, V. M. Shapovalov, E. V. Vorobyeva
Rok vydání:	2014
Předmět:	Inert chemistry.chemical_classification General Chemical Engineering Sorption Fraction (chemistry) General Chemistry Polymer Polyethylene engineering.material chemistry.chemical_compound Adsorption chemistry Chemical engineering Filler (materials) engineering Particle Organic chemistry
Zdroj:	Russian Journal of Applied Chemistry. 87:966-971
ISSN:	1608-3296 1070-4272
Popis:	The influence of chemically inert dispersed fillers (Al2O3, SiO2) on the efficiency of the polyethylene oxidation inhibition by commercial antioxidants (Irganox 1010, Neozon D) was studied. Introduction of chemically inert fillers into inhibited polymers alters the inhibitor distribution in the sample volume. The first fraction of the additive remains conventionally dissolved in the polymer (occurs in the dissolved state and in sorption sites), the second fraction is localized at the filler-polymer interface (separates out in the interfacial zone and accumulates in microcavities and voids of this zone), and the third fraction is adsorbed on the filler (forms an adsorption layer on the particle surface). As a result, the heat resistance of the filled polymer changes.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::77a48bd996672c3f687d2afba90fb7f5 https://doi.org/10.1134/s1070427214070192 Zobrazit plný text záznamu Full text from SpringerLink