Syntheses, Crystal Structures and Thermal Stability of Co(II) and Zn(II) Complexes with Ethyl Carbazate

Autor:	Jiang-Chuang Song, Tonglai Zhang, Jian-Guo Zhang, Gui-Xia Ma, Kai-Bei Yu
Rok vydání:	2005
Předmět:	Aqueous solution Inorganic chemistry Oxide chemistry.chemical_element General Chemistry Crystal structure Zinc Metal chemistry.chemical_compound chemistry visual_art visual_art.visual_art_medium Thermal stability Cobalt Nuclear chemistry Monoclinic crystal system
Zdroj:	Zeitschrift für Naturforschung B. 60:505-510
ISSN:	1865-7117 0932-0776
DOI:	10.1515/znb-2005-0505
Popis:	Cobalt(II) and zinc(II) complexes of ethyl carbazate (ECZ), [Co(ECZ)3](NO3)2 and [Zn(ECZ)3] (NO3)2, were synthesized. Single crystals of these two compounds were grown from aqueous solutions using a slow evaporation method. Their structures have been determined by X-ray diffraction analysis. Both of them are monoclinic with space group P21/n. The complexes are further characterized by element analysis and IR measurements. Their thermal stabilities are studied by using TG-DTG, DSC techniques. When heated to 350 °C, only metal oxide was left for both complexes.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::77a3c98be691aa0308e40e6217c7ba38 https://doi.org/10.1515/znb-2005-0505 Zobrazit plný text záznamu