Kubas complexes extended to four centers; a theoretical prediction of novel dihydrogen coordination in bimetallic tungsten and molybdenum compounds
| Autor: | Konstantinos Mertis, Emmanuel D. Simandiras, Dimitrios G. Liakos, Nikolaos Psaroudakis |
|---|---|
| Rok vydání: | 2014 |
| Předmět: |
Organic Chemistry
Inorganic chemistry Hydrogen molecule chemistry.chemical_element Tungsten Biochemistry Inorganic Chemistry chemistry.chemical_compound Crystallography chemistry Molybdenum compounds Molybdenum Theoretical methods Materials Chemistry Dihydrogen complex Physical and Theoretical Chemistry Bimetallic strip Phosphine |
| Zdroj: | Journal of Organometallic Chemistry. 766:67-72 |
| ISSN: | 0022-328X |
| Popis: | A number of molybdenum and tungsten bimetallic compounds with carbonyl and phosphine ligands are investigated, using theoretical methods, with respect to their ability to bind molecular hydrogen in a Kubas type coordination. Some are found to give novel complexes, containing a four center metal–dihydrogen interaction. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full Text from ScienceDirect