Crystal packing and reactivity of di(meth)acrylates of some derivatives of hydroquinone and pyrocatechol in melts

Autor: Georgy K. Fukin, Yu. V. Chechet, M. Yu. Zakharina, Gleb A. Abakumov, Alexander S. Shaplov, O. N. Mamysheva, Sergey A. Chesnokov
Rok vydání: 2010
Předmět:
Zdroj: Polymer Science Series B. 52:203-213
ISSN: 1555-6123
1560-0904
DOI: 10.1134/s1560090410030115
Popis: The X-ray diffraction study of 2,2′-(1,2-phenylene-bis(oxy)diethanol and 2,2′-(1,4-phenylenebis(oxy)diethanol dimethacrylates and 2,2′-(1,4-phenylenebis(oxy)diethanol diacrylate (T m = 40–42, 68–70, and 62–64°C, respectively) indicates that oligomer molecules are packed in crystals as stacks in which methacrylate fragments of adjacent molecules are parallel to each other. The minimum distances between the centers of C=C double bonds of adjacent methacrylate fragments in crystals of di(meth)acrylates are 4.373, 4.215, and 3.996 respectively. The conversion dependences of the reduced rates of photopolymerization of melted oligomers (9,10-phenanthrenequinone as a photoinitiator) pass through maxima at conversions of 40, 11, and 2%, while the ultimate conversions are 85, 33, and 73%, respectively. The addition of ionic liquids based on phosphonium and imidazolium cations to dimethacrylates of 2,2′-(1,2-phenylenebis(oxy)diethanol and triethylene glycol increases the maximum reduced rate of photopolymerization.
Databáze: OpenAIRE
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