A self assembled 3-D network propagated by coordination polymerization and H-bonding: synthesis and X-ray crystal structure of [{Co(L)2(H2O)2}(ClO4)2(CH3COCH3)2(H2O)2] n , where L = N,N-diisopropylisonicotinamide

Autor:	Ajay Pal Singh Pannu, Maninder Singh Hundal, Geeta Hundal, Martín Martínez-Ripoll, Pratibha Kapoor, Ramesh Kapoor
Rok vydání:	2011
Předmět:	Perchlorate chemistry.chemical_compound Crystallography chemistry Hydrogen bond Coordination polymer Materials Chemistry Cationic polymerization Supramolecular chemistry Coordination polymerization Crystal structure Physical and Theoretical Chemistry Single crystal
Zdroj:	Journal of Coordination Chemistry. 64:1566-1577
ISSN:	1029-0389 0095-8972
Popis:	Reaction of Co(ClO4)2 · 6H2O with N,N-diisopropylisonicotinamide (L) has yielded a 1-D coordination polymer [{Co(L)2(H2O)2}(ClO4)2(CH3COCH3)2(H2O)2] n (1). Complex 1 has been characterized by infrared (IR) and UV-Vis spectroscopies, thermal analysis, and single crystal X-ray diffraction techniques. The structure has alternate arrangement of parallel 1-D cationic metal-ligand chains and H-bonded anionic chains containing perchlorate, acetone and water in the lattice. Further hydrogen bonding among both chains leads to formation of 2-D networks along almost perpendicular planes. Interpenetrations of such perpendicular 2-D sheets create a 3-D supramolecular structure.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::73ba32b7c2879d3508ca8ca06c019fd6 https://doi.org/10.1080/00958972.2011.574286 Zobrazit plný text záznamu