The polymerization of aminoesters and their salts in various solvents

Autor:	Ye.D. Rogozhkina, A.P. Sheinker, A.L Izymnikov, Ye.V. Bune, A.D Abkin
Rok vydání:	1983
Předmět:	Kinetic chain length Chain-growth polymerization Bulk polymerization Polymerization Chemistry Polymer chemistry General Engineering Cationic polymerization Organic chemistry Solution polymerization Chain transfer Ionic polymerization
Zdroj:	Polymer Science U.S.S.R.. 25:106-113
ISSN:	0032-3950
Popis:	The elementary rate constants of propagation and termination for the polymerization of diethylaminoethyl methacrylate (DE) and its acetate and hydrochloride salts in various solvents have been determined. The correlation between the polymerization rate of DE acetate in dioxane-water mixtures of various compositions and the position of the νc=o frequencies of the monomer in these solvents was found. The increase in the rate of polymerization of DE and of its salts with its transfer from the organic solvents to water is a result of the formation of a hydrogen bond between the C=O group of the monomer and the solvent. The different conformations of the growing polymer chains due to a change in the degree of ionization of these monomers in solvents of different type also makes an essential contribution to the change in polymerization rate.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::72c927dc5acc4da35c0ee93e087ed7a0 https://doi.org/10.1016/0032-3950(83)90383-0 Zobrazit plný text záznamu