Thermodynamics of H+/H•/H–/e– Transfer from [CpV(CO)3H]−: Comparisons to the Isoelectronic CpCr(CO)3H

Autor:	Jack R. Norton, Thilina Gunasekara, Andreas Hansen, Fabian Bohle, Jonathan L. Kuo, Hunter B. Vibbert, Stefan Grimme, Patrick J. Quinlivan
Rok vydání:	2019
Předmět:	Inorganic Chemistry Crystallography 010405 organic chemistry Chemistry Organic Chemistry Free energies Hydrogen atom Physical and Theoretical Chemistry 010402 general chemistry 01 natural sciences Small molecule Dissociation (chemistry) 0104 chemical sciences
Zdroj:	Organometallics. 38:4319-4328
ISSN:	1520-6041 0276-7333
DOI:	10.1021/acs.organomet.9b00586
Popis:	Hydrogen atom (H•) donors generated from H2 facilitate the atom efficient reduction of small molecule substrates. However, generating H• donors with X–H bond dissociation free energies (BDFEs) belo...
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::727bd881712021a59b7f117f60ca2e6d https://doi.org/10.1021/acs.organomet.9b00586 Zobrazit plný text záznamu