Synthesis and structural characterization of two coordination polymers constructed by bis(4-(1H-imidazol-1-yl)phenyl)methanone and 5-(tert-butyl)isophthalate ligands

Autor:	Shu-Wen Sun, Shao-Fei Song, Gao-Feng Wang, Hong Sun, Wei-Bing Wang
Rok vydání:	2019
Předmět:	chemistry.chemical_classification 010405 organic chemistry chemistry.chemical_element General Chemistry Polymer 010402 general chemistry 01 natural sciences 0104 chemical sciences chemistry.chemical_compound chemistry Polymer chemistry Imidazole 5-tert-butyl isophthalate Cobalt Topology (chemistry)
Zdroj:	Zeitschrift für Naturforschung B. 74:261-265
ISSN:	1865-7117 0932-0776
DOI:	10.1515/znb-2018-0197
Popis:	Two coordination polymers, {[Co(bipmo)(tbip)]·3H2O} n (1) and {[Cd(bipmo)(tbip)]·3H2O} n (2) (bipmo=bis(4-(1H-imidazol-1-yl)phenyl)methanone, H2tbip=5-tert-butylisophthalic acid), were synthesized by solvothermal methods and structurally characterized by elemental analyses, infrared spectroscopy, and single-crystal X-ray diffraction. The results from single-crystal X-ray diffraction data indicate that the solid state structures of 1 and 2 consist of metal-aromatic carboxylate layers, which are pillared by weak interactions to generate a three-dimensional network. The topological structures of 1 and 2 are uninodal nets based on 3-connected nodes with the Schläfli symbol of {63}.
Databáze:	OpenAIRE
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