Enantioselective synthesis of natural (+)-dactyloxene-B and -C by actuation of oxonium ion-initiated pinacol rearrangement

Autor:	J. T. Negri, Leo A. Paquette, Marc D. Lord
Rok vydání:	1993
Předmět:	Stereochemistry Organic Chemistry Enantioselective synthesis Farnesol Pinacol rearrangement Sesquiterpene Biochemistry Direct route chemistry.chemical_compound chemistry Drug Discovery Organic chemistry Enantiomer Oxonium ion Methyl group
Zdroj:	Tetrahedron Letters. 34:5693-5696
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(00)73835-4
Popis:	A direct route is described for assembling the spirocyclic framework of two sesquiterpene ethers derived biogenetically from the cyclization of farnesol with rearrangement of a methyl group.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::71b194bea4e95eca5fc4a2f66aebe62d https://doi.org/10.1016/s0040-4039(00)73835-4 Zobrazit plný text záznamu