Target-Oriented Fuel Design for the Homogeneous Charge Autoignition Combustion Mode: A Case Study of a n-Heptane–PODE3–Ethanol Mixture. 2. Identification of a Functional Configuration of Fuel Components
| Autor: | Zhongchang Liu, Wei Mingzhi, Xiangkai Meng, Li Runzhao, Shicheng Hu, Xinglu Wang, Yongqiang Han, Yijin Cai, Manzhi Tan, Jing Tian, Yun Xu, Jizheng Zheng |
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| Rok vydání: | 2018 |
| Předmět: |
Work (thermodynamics)
Heptane Materials science Ethanol General Chemical Engineering Energy Engineering and Power Technology Autoignition temperature 02 engineering and technology 021001 nanoscience & nanotechnology medicine.disease_cause Combustion Decomposition Soot law.invention Ignition system chemistry.chemical_compound Fuel Technology 020401 chemical engineering Chemical engineering chemistry law medicine 0204 chemical engineering 0210 nano-technology |
| Zdroj: | Energy & Fuels. 33:31-49 |
| ISSN: | 1520-5029 0887-0624 |
| DOI: | 10.1021/acs.energyfuels.8b02761 |
| Popis: | This work provides the target-oriented fuel design concept for efficient, clean combustion and identifies the functional configuration of fuel components for the homogeneous charge autoignition (HCAI) combustion mode. The n-heptane–PODE3–ethanol mixture is applied to exemplify the fuel design process. The interaction among n-heptane, PODE3, and ethanol for the heat release process and the role of PODE3 and ethanol on the soot precursors (n-C4H3, C2H2, C3H3, CH3, C2H4, and C4H4) reduction are also discussed. The main conclusions are summarized below: First, the 60% n-heptane–20% PODE3–20% ethanol exhibits distinct low temperature heat release, first high temperature heat release (HTHR) and second HTHR which are contributed by PODE3/n-heptane, n-heptane/ethanol, and ethanol, respectively. The dominant rate controlling reactions for OH accumulation are H atom abstraction from n-heptane and ketohydroperoxide decomposition of n-heptane. Therefore, n-heptane is the major ignition source, while PODE3 works as th... |
| Databáze: | OpenAIRE |
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