Synthesis, spectroscopic and crystal structure investigation of [Cu(bzsmp)2Cl2];{bzsmp = 2-benzylsulfanyl-5-(2-methoxyphenyl)-1,3,4-oxadiazole}: cyclization of N2-[bis(benzylsulfanyl)methylene]-2-methoxybenzohydrazide to 2-benzylsulfanyl-5-(2-methoxyphenyl)-1,3,4 -oxadiazole during complexation

Autor:	Vaibhave Aggarwal, N. K. Singh, Madan Singh, U. P. Singh
Rok vydání:	2009
Předmět:	Inorganic Chemistry chemistry.chemical_compound Chemistry Ligand Stereochemistry Materials Chemistry Oxadiazole Chelation Crystal structure Physical and Theoretical Chemistry Methylene Ring (chemistry) Medicinal chemistry
Zdroj:	Polyhedron. 28:195-199
ISSN:	0277-5387
DOI:	10.1016/j.poly.2008.10.016
Popis:	The ligand N2-[bis(benzylsulfanyl)methylene]-2-methoxybenzohydrazide (N2-bmbh) (1) on reaction with CuCl2.2H2O yielded the mononuclear complex [Cu(bzsmp)2Cl2] (2) (2-benzylsulfanyl-5-(2-methoxyphenyl)-1,3,4-oxadiazole, bzsmp). Complex 2 has been characterized by analytical, spectroscopic and X-ray data. X-ray study of 2 reveals that the cyclized ligand 2-benzylsulfanyl-5-(2-methoxyphenyl)-1,3,4-oxadiazole (bzsmp) acts as neutral bidentate ligand to form six membered chelate ring and the presence of C–H⋯π (face to edge) and C–H⋯S and two type of C–H⋯Cl weak interactions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::6f56bb6421359e6cdbbc541190601ed8 https://doi.org/10.1016/j.poly.2008.10.016 Zobrazit plný text záznamu Full Text from ScienceDirect