Growth and investigation on novel single crystal of β-cyclodextrin 2, 4-dinitrophenylhydrazine for optical sensors applications
| Autor: | M. Senthil Kumar, Suresh Varadarajan, S. Shanmugan, V. Chithambaram, V. Gandhimathi, P. Saminathan |
|---|---|
| Rok vydání: | 2020 |
| Předmět: |
010302 applied physics
Diffraction Materials science Infrared Analytical chemistry 02 engineering and technology 021001 nanoscience & nanotechnology 01 natural sciences Evaporation (deposition) Crystal Wavelength 0103 physical sciences Grain boundary Fourier transform infrared spectroscopy 0210 nano-technology Single crystal |
| Zdroj: | Materials Today: Proceedings. 30:45-51 |
| ISSN: | 2214-7853 |
| DOI: | 10.1016/j.matpr.2020.04.113 |
| Popis: | Nonlinear optical (NLO) 2, 4-Dinitrophenylhydrazine (DNPH) single crystal was grown by slow evaporation solution growth method at ambient temperature. The characterization of Powder X – Ray diffraction peaks was confirmed the new crystalline system. Fourier transform infrared spectroscopic analysis (FTIR) was used to the identification of various functional groups present in the grown crystal. The range of optical transmittance exhibited by the grown βCD-DNPH crystal was investigated by UV Visible – NIR spectral analysis. The lower cut off wavelength of the grown crystal is observed at 270 nm. The SEM figures are recorded in different magnification. It is clear that the surface of the grown crystal appears very smooth although it has pots and microcrystal on the surface. The grain boundaries are clearly seen which shows the perfect growth of the crystal. The weight percentage (wt %) of C, N and O as obtained from EDAX analysis is in concurrent with the theoretical values. The SHG efficiency of the grown crystal was determined. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full Text from ScienceDirect