Extractive Recovery and Separation of Palladium(II) from Model Hydrochloric Solution from Refining Shop with Di-n-Heptyl Sulfide and Penconazole
| Autor: | Yu. I. Murinov, R. A. Khisamutdinov, L. G. Golubyatnikova |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
chemistry.chemical_classification
Aqueous solution Chloroform Sulfide General Chemical Engineering Extraction (chemistry) chemistry.chemical_element 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Ammonia chemistry.chemical_compound chemistry Reagent 0210 nano-technology Platinum Palladium Nuclear chemistry |
| Zdroj: | Russian Journal of Applied Chemistry. 92:31-34 |
| ISSN: | 1608-3296 1070-4272 |
| DOI: | 10.1134/s107042721901004x |
| Popis: | Extractive method for recovery of palladium(II) from a model palladium-rich hydrochloric solution from a refining shop was suggested. It was found that palladium(II) is fully extracted with di-n-heptyl sulfide and penconazole from 3 M hydrochloric solutions with high salt background, with the optimal phase contact duration being 20 and 5 min, respectively. As reagent dilutions served toluene and chloroform. Palladium(II) was back-extracted with a 15% aqueous ammonia and a saturated aqueous solution of sodium rhodanide. The optimal conditions of palladium(II) extraction and its separation from the accompanying platinum(IV) and copper(II). |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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