Reduction of Cyclic and Linear Organic Carbonates Using a Readily Available Magnesium Catalyst
| Autor: | Marc Magre, Viktoriia Zubar, Marcin Szewczyk, Magnus Rueping |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
Reaction conditions
010405 organic chemistry Magnesium Depolymerization Inorganic chemistry chemistry.chemical_element General Chemistry 010402 general chemistry 01 natural sciences Catalysis 0104 chemical sciences Reduction (complexity) Hydroboration chemistry.chemical_compound chemistry Carbon dioxide Earth (classical element) |
| Zdroj: | ACS Catalysis. 9:11634-11639 |
| ISSN: | 2155-5435 |
| Popis: | Efficient reduction of cyclic and linear organic carbonates catalyzed by a readily available earth alkaline catalyst has been achieved. The described homogenous reaction based on a ligand-free magnesium catalyst provides an indirect route for the conversion of CO2 into valuable alcohols. The reaction proceeds with high yields under mild reaction conditions, with low catalyst loading and short reaction times, and shows a broad applicability toward various linear and cyclic carbonates. Additionally, it can be applied for the depolymerization of polycarbonates. |
| Databáze: | OpenAIRE |
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