Synthesis of Palladium Nanoparticle by Bio-reduction Method and Its Effectiveness as Heterogeneous Catalyst Towards Selective Oxidation of Benzyl Alcohols in Aqueous Media
| Autor: | Porismita Bordoloi, Pradip K. Gogoi, Nibedita Gogoi, Geetika Borah |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
010405 organic chemistry
Reducing agent Nanoparticle chemistry.chemical_element General Chemistry 010402 general chemistry Heterogeneous catalysis 01 natural sciences Catalysis 0104 chemical sciences chemistry.chemical_compound Montmorillonite chemistry Alcohol oxidation Organic chemistry BET theory Nuclear chemistry Palladium |
| Zdroj: | Catalysis Letters. 147:539-546 |
| ISSN: | 1572-879X 1011-372X |
| DOI: | 10.1007/s10562-016-1937-9 |
| Popis: | Monodispersed palladium nanoparticles (PdNp) have been synthesized by a green rapid bio-reduction method under room temperature and pressure. The reducing agents mainly involved in these processes are the various water soluble plant metabolites, polyphenols as well as co-enzymes present in the leaf extract of Tulsi (Ocimum sanctum). An active and stable montmorillonite K-10 supported heterogeneous catalyst was prepared using these PdNp for oxidation of alcohols to their corresponding carbonyl compounds with efficient yield and having good reusability. These are characterized by TEM, XRD, BET surface area and UV–Vis absorption spectroscopy. |
| Databáze: | OpenAIRE |
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