Oxomolybdenum(IV,V,VI) complexes: structures, reactivities, and criteria of detection of binuclear (.mu.-oxo)molybdenum(V) products in oxygen atom transfer systems

Autor:	M. A. Whitener, Julia A. Craig, B. S. Snyder, Edgar W. Harlan, Richard H. Holm
Rok vydání:	1989
Předmět:	Schiff base Stereochemistry chemistry.chemical_element Nuclear magnetic resonance spectroscopy Crystal structure Medicinal chemistry Inorganic Chemistry Solvent chemistry.chemical_compound chemistry Molybdenum X-ray crystallography Molecule Physical and Theoretical Chemistry Solubility
Zdroj:	Inorganic Chemistry. 28:2082-2091
ISSN:	1520-510X 0020-1669
DOI:	10.1021/ic00310a015
Popis:	A series of dioxo-Mo(VI) Schiff base complexes of the type MoO 2 (R-L)(solv) has been prepared: L=2-(salicylideneamino)-phenolate(2-) (sap) or 2-(salicylideneamino)benzenethiolato(2-) (ssp); solv=solvent. Salicylidene ring substituents R were selected to promote solubility and crystallinity. The unsubstituted complexes MoO 2 (sap)(solv) and MoO 2 (ssp)(solv) have been previously reported. The structures of two members of the series were determined
Databáze:	OpenAIRE
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