Economic Large-Scale Synthesis of o- and m-Diphenylphosphinobenzoic Acids

Autor:	Susanne T. Kemme, Bernhard Breit, Andy Ch. Laungani, Christian Herber, Christian U. Grünanger, Yvonne Schmidt
Rok vydání:	2010
Předmět:	chemistry.chemical_compound chemistry Scale (ratio) Organic Chemistry Organic chemistry Crystallographic data Single step Triphenylphosphine Combinatorial chemistry Catalysis
Zdroj:	Synthesis. 2010:1924-1928
ISSN:	1437-210X 0039-7881
Popis:	An efficient and simple to perform large-scale synthesis of O- and M-diphenylphosphinobenzoicacids is presented. In a single step, both useful carboxylic acid-functionalizedphosphines can be accessed starting from the same inexpensive bulkchemicals O-chlorobenzoic acid, triphenylphosphine,and sodium. In both cases the formation of the desired product iscontrolled by the ratio of the starting materials only. Additionally,X-ray crystallographic data are reported for both products.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::6b668973be15de57911c93ac169ce935 https://doi.org/10.1055/s-0029-1218705 Zobrazit plný text záznamu