Phosphine-catalyzed hydroboration of propiolonitriles: access to (E)-1,2-vinylcyanotrifluoroborate derivatives

Autor:	Johnathan Bowen, Carla Slebodnick, Webster L. Santos
Rok vydání:	2022
Předmět:	Materials Chemistry Metals and Alloys Ceramics and Composites General Chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials
Zdroj:	Chemical Communications. 58:5984-5987
ISSN:	1364-548X 1359-7345
DOI:	10.1039/d2cc00603k
Popis:	We report an organocatalytic trans hydroboration of 3-substituted-propiolonitriles. The reaction proceeds through a 1,2-phosphine addition instead of a canonical 1,4-conjugate addition pathway.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::6b5d365c025384f008383d7cf5443e0c https://doi.org/10.1039/d2cc00603k Zobrazit plný text záznamu