Synthesis of polymeric bismuth chlorido hydroxamato complexes; X-ray crystal structure and antibacterial activity of a novel Bi(III) salicylhydroxamato complex
| Autor: | Lauren E. Fagan, Darren M. Griffith, Brid Quilty, Donal M Keogan, Thayse Marques Passos, Helge Müller-Bunz |
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| Rok vydání: | 2017 |
| Předmět: |
Hydroxamic acid
010405 organic chemistry Stereochemistry Ligand X-ray chemistry.chemical_element Crystal structure 010402 general chemistry 01 natural sciences Salicylhydroxamic acid 0104 chemical sciences Bismuth Inorganic Chemistry chemistry.chemical_compound chemistry Polymer chemistry Materials Chemistry Physical and Theoretical Chemistry Antibacterial activity |
| Zdroj: | Inorganica Chimica Acta. 460:134-140 |
| ISSN: | 0020-1693 |
| DOI: | 10.1016/j.ica.2016.09.021 |
| Popis: | Reaction of salicylhydroxamic acid (Sha) and 2-aminophenyl hydroxamic acid (2-NH2-pha) with BiCl3 affords the corresponding novel polymeric bismuth chlorido hydroxamato complexes; [BiCl2(μ-Sha-1H)]∞ and [BiCl3(2-NH3-Pha-1H)]∞ respectively. The X-ray crystal structure of the THF-solvated polymeric bismuth chlorido salicylhydroxamato complex, [BiCl2(μ-Sha-1H)(THF)]∞ was solved, confirming the polymeric structure of this class of compounds and the (O,μ-O′)-bidentate bridging coordination mode of the hydroxamato ligand. The antibacterial activity of the THF-free polymeric bismuth chlorido salicylhydroxamato complex, [BiCl2(μ-Sha-1H)]∞, was investigated against a broad panel of bacteria, further highlighting the antibacterial properties of Bi-based compounds against Gram-positive and Gram-negative pathogenic and environmental strains of bacteria. |
| Databáze: | OpenAIRE |
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