Nature of H-bonds in water vapor
| Autor: | Mikhail V. Timofeev, Nikolay P. Malomuzh, I.V. Zhyganiuk |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
Work (thermodynamics)
Chemistry Hydrogen bond Dimer Electron shell 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences Atomic and Molecular Physics and Optics 0104 chemical sciences Electronic Optical and Magnetic Materials Degree (temperature) chemistry.chemical_compound Interaction potential Chemical physics Computational chemistry Materials Chemistry Molecule Physical and Theoretical Chemistry 0210 nano-technology Spectroscopy Water vapor |
| Zdroj: | Journal of Molecular Liquids. 242:175-180 |
| ISSN: | 0167-7322 |
| DOI: | 10.1016/j.molliq.2017.06.127 |
| Popis: | The work is devoted to the discussion of the H-bond nature in rare enough water vapor. For achievement of this aim 1) the new inter-particle potential between water molecules is constructed and 2) the overlapping degree of electron shells for water molecules forming an isolated dimer is in details studied. In order to estimate the diameter of a molecule, the averaged inter-particle potential between water molecules is used. It is shown that the overlapping degree does not exceed 0.03 that leads to the conclusion about the electrostatic nature of H-bonds in water vapor. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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