Multifunctional polymers with interpenetrating structures: luminescence sensing, ECL behaviors, selective detection of Fe3+ ion and rapid removal of anionic dyes

Autor: Lingshu Meng, Lun Zhao, Guanlin Guo, Xin Liu
Rok vydání: 2020
Předmět:
Zdroj: New Journal of Chemistry. 44:9025-9036
ISSN: 1369-9261
1144-0546
DOI: 10.1039/d0nj01066a
Popis: Three novel 3D coordination polymers (CPs), {[Cd(L)(bimb)](H2O)4}n (1), {[Zn(L)(bibp)](H2O)(DMF)}n (2) and {[Zn(L)(bif)](H2O)4}n (3) (bimb = 1,4-bis(imidazoly-1-yl)benzene, bibp = 4,4′-bis(imidazol-1-yl)biphenyl, bif = 2,7-bis(1-imidazoly)fluorene, H2L = 1-(4-carboxylphenyl)piperidine-4-caboxylic acid) have been synthesized under solvothermal conditions. Compound 1 featured a 5-fold interpenetration of the 4-c dia net. Compound 2 and 3 presented a 6-fold interpenetration of the 4-c dia net. Moreover, their luminescence properties and the selective detection of Fe3+ ion for 1 were investigated. In addition, the adsorption ability of 1 and 2 toward dye molecules was tested, respectively. Furthermore, their ECL behaviors were tested.
Databáze: OpenAIRE