Headspace gas chromatographic separation of toxic organic impurities from air

Autor:	V. N. Filimonov, N. N. Garkavaya, L. N. Balyatinskaya
Rok vydání:	1997
Předmět:	chemistry.chemical_classification Ethanol Chromatography Ketone Chemistry Organic Chemistry Clinical Biochemistry Primary alcohol Biochemistry Analytical Chemistry Methyl isobutyl ketone chemistry.chemical_compound Acetone Methanol Gas chromatography Effluent
Zdroj:	Chromatographia. 45:343-346
ISSN:	1612-1112 0009-5893
DOI:	10.1007/bf02505581
Popis:	To determine toxic organic compounds (methanol, ethanol, n-propanol, acetone, methyl ethyl ketone, methyl isobutyl ketone) in air a method was developed for their headspace gas chromatographic analysis with preconcentration in n-butanol (alcohols) and in n-pentanol (ketones). The distribution coefficients of analytes in the air-absorbent system have been measured: 1051 (MeOH), 5630 (EtOH), 6773 (n-PrOH), 307 (Me2CO), 580 (MeCOEt), 1035 (MeCOBu-i). The minimum detectable level (mg m−3) was determined as low as 0.9 (MeOH), 4.0 (EtOH), 0.9 (n-PrOH), 0.2 (Me2CO), 0.1 (MeCOEt), 0.4 (MeCOBu-i). The method was effectively used for gas effluent air control in the workplace and in the atmosphere.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::66e8b21984e2a8b19c2344091ea6983d https://doi.org/10.1007/bf02505581 Zobrazit plný text záznamu Full text from SpringerLink