Effect of water on decomposition of formic acid over V–Ti oxide catalyst: Kinetic and in situ FTIR study

Autor:	Tamara V. Andrushkevich, Yuriy A. Chesalov, E.M. Sadovskaya, Galina Ya. Popova
Rok vydání:	2012
Předmět:	Formic acid Process Chemistry and Technology Inorganic chemistry Oxide Decomposition Catalysis Reversible reaction chemistry.chemical_compound Adsorption chemistry mental disorders Formate Physical and Theoretical Chemistry Fourier transform infrared spectroscopy
Zdroj:	Journal of Molecular Catalysis A: Chemical. 357:148-153
ISSN:	1381-1169
DOI:	10.1016/j.molcata.2012.02.005
Popis:	Decomposition of formic acid over V–Ti oxide catalyst in the absence and in the presence of water was studied by kinetic and in situ FTIR methods. CO and CO2 in a ratio of ∼9/1 are the products of decomposition of formic acid. Surface bidentate and monodentate formate ions are the products of formic acid adsorption at 120–140 °C. Decrease in the rate of formic acid decomposition in the presence of water observed in the steady-state kinetic experiments is related with the competitive adsorption between H2O and formic acid and with the acceleration of the reverse reaction of formic acid formation from formates.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::66e0a9982bb00f55b1996ea64b363520 https://doi.org/10.1016/j.molcata.2012.02.005 Zobrazit plný text záznamu Full Text from ScienceDirect