Gas Absorption by Cobalt Soaps
Autor: | Hideo Funakoshi |
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Rok vydání: | 1962 |
Předmět: | |
Zdroj: | Bulletin of the Chemical Society of Japan. 35:1025-1029 |
ISSN: | 1348-0634 0009-2673 |
DOI: | 10.1246/bcsj.35.1025 |
Popis: | The gas absorption by cobalt oleate and stearate has been studied. It was found that cobalt oleate absorbs oxygen very remarkably, but nitrogen and hydrogen, very little. Cobalt stearate absorbs oxygen negligibly, but in the presence of oleic acid the absorption becomes considerable. From the studies of ultraviolet and infrared spectra and X-ray analysis of the oxygen absorption by cobalt oleate, it was found that oxygen is coordinated by the cobalt atom and destroys the double bond structure. The probable mechanism of the catalytic action of cobalt soaps has also been presented. |
Databáze: | OpenAIRE |
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