Gas Absorption by Cobalt Soaps

Autor: Hideo Funakoshi
Rok vydání: 1962
Předmět:
Zdroj: Bulletin of the Chemical Society of Japan. 35:1025-1029
ISSN: 1348-0634
0009-2673
DOI: 10.1246/bcsj.35.1025
Popis: The gas absorption by cobalt oleate and stearate has been studied. It was found that cobalt oleate absorbs oxygen very remarkably, but nitrogen and hydrogen, very little. Cobalt stearate absorbs oxygen negligibly, but in the presence of oleic acid the absorption becomes considerable. From the studies of ultraviolet and infrared spectra and X-ray analysis of the oxygen absorption by cobalt oleate, it was found that oxygen is coordinated by the cobalt atom and destroys the double bond structure. The probable mechanism of the catalytic action of cobalt soaps has also been presented.
Databáze: OpenAIRE