Induced Circular Dichroism Spectra of β- and γ-Cyclodextrin Complexes with Indazolinone and Related Compounds

Autor:	Miwako Higashi, Masahiro Kawamura
Rok vydání:	2005
Předmět:	chemistry.chemical_classification Circular dichroism Cyclodextrin Magnetic circular dichroism Dimer General Chemistry Condensed Matter Physics Tautomer Quinone chemistry.chemical_compound Crystallography chemistry Molecule ZINDO Food Science
Zdroj:	Journal of Inclusion Phenomena and Macrocyclic Chemistry. 51:11-15
ISSN:	1573-1111 0923-0750
DOI:	10.1007/s10847-004-5390-9
Popis:	The magnetic circular dichroism (MCD) spectra of indazolinone, isatine, and 3-iminoisoindolinone and the induced circular dichroism (ICD) spectra of the inclusion complexes with β- or γ-cyclodextrins (CDs) have been measured. The spectra are interpreted by results of the ZINDO calculations. In the presence of cyclodextrin, the OH indazolinone tautomer is main structure that is consistent with that in the DMSO solution. The structures of the inclusion complexes are very different because of the scale of the cavity of cyclodextrin or position of quinone in molecules.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::64d9ab16137b0dbd289de44639c876cb https://doi.org/10.1007/s10847-004-5390-9 Zobrazit plný text záznamu Full text from SpringerLink