Resolving the Two-Electron Process for the Couple [(C5Me5)M(N∧N)Cl]+/[(C5Me5)M(N∧N)] (M = Rh, Ir) into Two One-Electron Steps Using the 2,2‘-Azobis(pyridine) N∧N Ligand, Fast Scan Cyclovoltammetry, and Spectroelectrochemistry: Detection of Radicals instead of MII Intermediates

Autor:	Wolfgang Kaim, Ralf Reinhardt, Stefan Greulich, Jan Fiedler
Rok vydání:	2003
Předmět:	Ligand Stereochemistry Radical Organic Chemistry Fast scanning Electron law.invention Inorganic Chemistry Crystallography chemistry.chemical_compound chemistry law Pyridine Physical and Theoretical Chemistry Electron paramagnetic resonance
Zdroj:	Organometallics. 22:2240-2244
ISSN:	1520-6041 0276-7333
Popis:	The complex cations [(C5Me5)M(abpy)Cl]+ (M = Rh, Ir; abpy = 2,2‘-azobis(pyridine)) are reduced to the coordinatively unsaturated compounds [(C5Me5)M(abpy)] via the EPR and UV/vis spectroelectrochem...
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::6489fd22475c53020ec976b6d6dbd26c https://doi.org/10.1021/om020860j Zobrazit plný text záznamu