Synthesis, bridgehead functionalization, and photoisomerization of 9,10-diboratatriptycene dianions
| Autor: | Sven E. Prey, Jannik Gilmer, Samira V. Teichmann, Luis Čaić, Mischa Wenisch, Michael Bolte, Alexander Virovets, Hans-Wolfram Lerner, Felipe Fantuzzi, Matthias Wagner |
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| Rok vydání: | 2023 |
| Předmět: | |
| Zdroj: | Chemical Science. 14:5316-5322 |
| ISSN: | 2041-6539 2041-6520 |
| DOI: | 10.1039/d3sc00555k |
| Popis: | 9,10-Diboratatriptycene dianions were synthesized via [4 + 2] cycloaddition between 9,10-dihydro-9,10-diboraanthracene dianions and benzyne. We show bridgehead chlorination, Me2S-adduct formation, and photorearrangement to diborabenzo[a]fluoranthenes. |
| Databáze: | OpenAIRE |
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