B-Substituted Carboranyl Thio- and Selenophosphites. Synthesis and Chemical Properties

Autor: Godovikov Nn, M. I. Kabachnik, V. P. Balema, E. G. Rys
Rok vydání: 1996
Předmět:
Zdroj: Phosphorus, Sulfur, and Silicon and the Related Elements. 111:115-115
ISSN: 1042-6507
DOI: 10.1080/10426509608054744
Popis: The first examples of B-substituted carboranyl thio- and selenoesters of trivalent phosphorus acids were synthesized. On the basis of these samples, a series of new corresponding pentavalent phosphorus acids derivatives, potentialy bioactive compounds, was obtained. S- and Se-carborane-9-yl-diethyl-thiophosphites (I) were obtained by the interaction of diethylchlorphosphites with 9-mercapto- or 9-selenocarboranes in the presence of triethylamine.
Databáze: OpenAIRE