Electronic Structures of [RuII(cyclam)(Et2dtc)]+, [Ru(cyclam)(tdt)]+, and [Ru(cyclam)(tdt)]2+: An X-ray Absorption Spectroscopic and Computational Study (tdt = toluene-3,4-dithiolate; Et2dtc = N,N-diethyldithiocarbamate(1-))

Autor:	Karl Wieghardt, Carsten Milsmann, Serena DeBeer George, Thomas Weyhermüller, Eckhard Bill
Rok vydání:	2009
Předmět:	Inorganic Chemistry chemistry.chemical_compound chemistry Cyclam X-ray Methanol Physical and Theoretical Chemistry Absorption (chemistry) Photochemistry Toluene Medicinal chemistry
Zdroj:	Inorganic Chemistry. 48:9754-9766
ISSN:	1520-510X 0020-1669
DOI:	10.1021/ic9011845
Popis:	The reaction of [RuIII(cyclam)Cl2]Cl with 2 equiv of sodium N,N-diethyldithiocarbamate in methanol afforded [RuII(cyclam)(Et2dtc)](BPh4) (1(BPh4)). The same reaction with only 1 equiv of toluene-3,...
Databáze:	OpenAIRE
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