Fourier Transform Infrared Spectrum and Rotational Structure of the A-Type 917.5 cm−1 Band of Nitromethane
| Autor: | R. J. Kshirsagar, Anindya Hazra, Pradip N. Ghosh |
|---|---|
| Rok vydání: | 1994 |
| Předmět: |
Materials science
Absorption spectroscopy Nitromethane Infrared Infrared spectroscopy Atomic and Molecular Physics and Optics symbols.namesake chemistry.chemical_compound Fourier transform Nuclear magnetic resonance chemistry symbols Wavenumber Rigid rotor Physical and Theoretical Chemistry Atomic physics Hamiltonian (quantum mechanics) Spectroscopy |
| Zdroj: | Journal of Molecular Spectroscopy. 164:20-26 |
| ISSN: | 0022-2852 |
| DOI: | 10.1006/jmsp.1994.1054 |
| Popis: | The high-resolution Fourier transform infrared spectrum of nitromethane has been measured to obtain the rotation-internal rotation structure of the A-type CN stretching band at 917.5 cm−1. For the methyl rotor m = 0 state vibration-rotation transition, have been analyzed on the basis of the rigid rotor Hamiltonian. Altogether 1414 transitions up to J = 40, Ka = 38 are used in a least-squares fit program to obtain the center wave number and the effective rotational and centrifugal distortion constants of the upper state. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|