Development of an Attrition Resistant Fischer–Tropsch Catalyst for Slurry Operation
Autor: | Edvard Bergene, Erling Rytter, Øyvind Borg, Torild Hulsund Skagseth, Dag Schanke, Sigrid Eri, Hanne Wigum |
---|---|
Rok vydání: | 2011 |
Předmět: | |
Zdroj: | Topics in Catalysis. 54:801-810 |
ISSN: | 1572-9028 1022-5528 |
DOI: | 10.1007/s11244-011-9705-y |
Popis: | Resistance towards attrition, sufficient activity at end-of-run and high selectivity to desired products are some of the requirements for a slurry Fischer–Tropsch catalyst. We have found that modifying an alumina support by 2-valent metals, including magnesium, nickel and zinc, followed by high temperature firing, results in superior mechanical and ‘chemical attrition’ (dissolution) resistance of the catalyst. Further, a sufficiently high surface area is being stabilized. The catalyst performance has been verified in a long term test in a semi-commercial plant, including very good wax separation and high wax purity. Combined with appropriate process conditions, stable long-term operation of the catalyst is secured. |
Databáze: | OpenAIRE |
Externí odkaz: |