Synthesis and structure of monoclinic bismuth vanadate doped with molybdenum

Autor: K. Terebilenko, Nikolai Slobodyanik, Kostyantin Bychkov, Vyacheslav N. Baumer
Rok vydání: 2014
Předmět:
Zdroj: International Conference on Oxide Materials for Electronic Engineering - fabrication, properties and applications (OMEE-2014).
DOI: 10.1109/omee.2014.6912338
Popis: The synthetic conditions of BiVO 4 :Mo crystallization in the molten salts of K-Bi-V-Mo-O have been studied. The compound crystallizes in the monoclinic system, space group I2/a, with unit cell parameters a = 5.1153(3), b = 11.7012(1), c = 5.1878(1) A, β = 90.24(1)°, Z = 4 representing scheelite-related structure. The formula of the compound established to be Bi 0.98 V 0.95 Mo 0.05 O 4 .
Databáze: OpenAIRE