Covalent Organic Frameworks with High Charge Carrier Mobility

Autor: J. Fraser Stoddart, Omar M. Yaghi, Shu Seki, Sanjeev K. Dey, Lei Liao, Felipe Gándara, Atsushi Asano, Michael W. Ambrogio, Shun Wan, Youssry Y. Botros, Akinori Saeki, Xiangfeng Duan, Hiroyasu Furukawa
Rok vydání: 2011
Předmět:
Zdroj: Chemistry of Materials. 23:4094-4097
ISSN: 1520-5002
0897-4756
Popis: Two types (imine and boronate) of covalent organic frameworks (COFs) having a porphyrin unit have been synthesized. The two highly crystalline porphyrin COFs (COF-366 and COF-66) display excellent chemical and thermal stability and are permanently porous. Two-dimensional extended layered structures of the two COFs demonstrate very high charge carrier mobility values (8.1 cm2 V−1 s−1).
Databáze: OpenAIRE