Crystal Structure and Physicochemical Properties of Two Supramolecular Compounds: (C4H8NH2)4[Mo8O26] and (NH4)Na2[AsIIIMo6O21(O2CCH2NH3)3]·8H2O

Autor:	Amor Haddad, Meriem Ayed, Safa Thabet
Rok vydání:	2013
Předmět:	Materials science Polymers and Plastics Hydrogen bond Inorganic chemistry Supramolecular chemistry Infrared spectroscopy Crystal structure chemistry.chemical_compound Crystallography chemistry Materials Chemistry Molecule Thermal stability Carboxylate Thermal analysis
Zdroj:	Journal of Inorganic and Organometallic Polymers and Materials. 24:291-301
ISSN:	1574-1451 1574-1443
DOI:	10.1007/s10904-013-9892-z
Popis:	Two inorganic–organic hybrid supramolecular compounds based on polyoxometalates formulated as (C4H8NH2)4[Mo8O26] (1) and (NH4)Na2[AsIIIMo6O21(O2CCH2NH3)3]·8H2O (2) have been synthesized by conventional solution method and characterized by infrared, UV–Vis and single-crystal X-ray diffraction analyses. Thermal analysis was performed to study their thermal stability. The atomic arrangement in compound (1) can be described as inorganic layers built by [Mo8O26]4−, pyrrolidinium cations are embedded into layers. The fascinating structural feature of compound (2) is that the glycine molecules are bounded to two edge-sharing Mo centers via their carboxylate functionality leading to functionalized heteropolymolybdate [AsIIIMo6O21(O2CCH2NH3)3]3−, extensive net hydrogen bonds between cations and anions contribute to the crystal packing. The electrochemical behavior of compound (2) has been studied.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5eab720f0470345b654d48d5310cbbf0 https://doi.org/10.1007/s10904-013-9892-z Zobrazit plný text záznamu Full text from SpringerLink