The Electrochemical Impedance of the Na/S Cell: I . Experiments and Results
| Autor: | Michael C. H. McKubre, F. L. Tanzella, S. I. Smedley |
|---|---|
| Rok vydání: | 1989 |
| Předmět: |
Electromotive force
Renewable Energy Sustainability and the Environment Open-circuit voltage Chemistry Analytical chemistry Condensed Matter Physics Electrochemistry Surfaces Coatings and Films Electronic Optical and Magnetic Materials law.invention law Electrode Materials Chemistry Constant current Resistor Electrical impedance Voltage |
| Zdroj: | Journal of The Electrochemical Society. 136:1962-1968 |
| ISSN: | 1945-7111 0013-4651 |
| Popis: | We have carried out a number of experiments to characterize some electrochemical properties of a Na/S cell. They were: measurements of the cell EMF, cell voltage and current on charge and discharge, both at constant current and with stepped currents; cell impedance from 0.5 mHz to 10 kHz; and measurements of the relaxation of the open-circuit voltage. At the onset of the single phase region in the sulfur electrode, the cell impedance from 5 to 0.5 mHz rises to a maximum due to the onset of a diffusion controlled process. The measurements of cell voltage and current confirm this experimental result |
| Databáze: | OpenAIRE |
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