A Novel Aqua Ligand Assisted Water Octamer Confinement in the Hydrophilic Channels of a Zn(II) Supramolecular Architecture

Autor:	Wei-Xia, Ya-Ping Duan, Dongsheng Li, Wen-Wen Dong, Jun Zhao
Rok vydání:	2014
Předmět:	Crystallography Polymers and Plastics Chemistry Hydrogen bond Ligand Inorganic chemistry Materials Chemistry Supramolecular chemistry Molecule Thermal stability Histone octamer Water cluster Fluorescence
Zdroj:	Journal of Inorganic and Organometallic Polymers and Materials. 24:796-801
ISSN:	1574-1451 1574-1443
Popis:	A new two-dimensional polymeric [Zn2(4-pzpt)(btc)(H2O)2·3H2O] (1) (4-Hpzpt = 3-(pyridin-4-yl)-5-(pyrazin-2-yl)-1H-1,2,4-triazole, H3btc = 1,2,3-benzenetricarboxylate), has been synthesized and structurally characterized and features a 3D supramolecular framework with 1D hydrophilic channels formed by the interlayer hydrogen bonds. An unprecedented aqua ligand assisted octameric water cluster consisting of a quasiplanar cyclic hexameric core and two dangling water molecules is captured in 1. The thermal stability and solid state fluorescent property of 1 are discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::5cb56a7c28c532a035af763c8f478e76 https://doi.org/10.1007/s10904-014-0033-0 Zobrazit plný text záznamu Full text from SpringerLink