Reaction of 1H-1-oxo-2,4,6,8-tetrakis(tert-butyl) phenoxazine with certain group II?IV metals
| Autor: | O. Yu. Okhlobystin, A. I. Prokof'ev, V. S. Khandkarova, M. I. Kabachnik, I. V. Karsanov, A. Z. Rubezhov, Vladimir I. Minkin, E. P. Ivakhnenko |
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| Rok vydání: | 1987 |
| Předmět: |
Chemistry
Inorganic chemistry General Chemistry Resonance (chemistry) law.invention Chemical kinetics Metal Hydrolysis chemistry.chemical_compound law visual_art Kinetic isotope effect Polymer chemistry visual_art.visual_art_medium Electron paramagnetic resonance Phenoxazine Group 2 organometallic chemistry |
| Zdroj: | Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 36:60-64 |
| ISSN: | 1573-9171 0568-5230 |
| Popis: | 1. In the reaction of 1H-1-oxo-2,4,6,8-tetrakis(tert-butyl)phenoxazine with amalgams of the II–IV group metals, paramagnetic complexes are formed of mono-, bi- and triradical types, according to the nature of the reacting metal. 2. Monoradical complexes with Al are formed as a result of successive hydrolysis of the triradical by traces of moisture. |
| Databáze: | OpenAIRE |
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